W. Stöber, A. Fink and E. Bohn,Controlled growth of monodisperse silica spheres in micron size range,J. Colloid Interface Sci.,1968,26(1), 62-69.
A system of chemical reaction has been developed which permit the controlled growth of spherical silica particles of uniform size by means of hydrolysis of alkyl silicates and subsequent condensation of silicic acid in alcoholic solutions. Ammonia is used as a morphological catalyst. Particle sizes obtained in suspension range from less than 0.05 um to 2 um in diameter.